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How to Choose Functional Silicone Fluids (Modified Silicone Oil)

Choose Functional Silicone Fluids

Functional silicone fluids, also called modified silicone oils, are polydimethylsiloxane (PDMS) molecules chemically modified with functional groups to impart additional properties.
These groups—such as amino, hydroxyl, epoxy, vinyl, polyether, or phenyl—enhance reactivity, compatibility, lubrication, water repellency, anti-static behavior, and emulsification.

Compared to standard linear silicone oils, functional silicone fluids are used in textiles, coatings, cosmetics, lubricants, release agents, and electronics, offering specialized performance beyond basic thermal stability and chemical inertness.

Silico® functional silicone fluids are high-purity, professionally modified products designed for reliable performance in industrial, cosmetic, and specialty applications.

1. Differences Between Modified and Linear Silicone Oils

FeatureLinear Silicone OilFunctional (Modified) Silicone Oil
StructurePDMS chain with simple end groupsPDMS chain modified at end or side with functional groups (amino, epoxy, hydroxyl, polyether, phenyl)
PropertiesHeat stable, chemically inert, lubricatingEnhanced adhesion, compatibility, softening, anti-static, emulsification
ApplicationsThermal fluids, damping oils, electrical insulationTextiles, coatings, cosmetics, release agents, electronics

Functional groups allow targeted performance improvements, such as fabric softening, anti-static, mold release, lubrication, or emulsification, which standard PDMS cannot achieve.

2. Types of Functional Silicone Fluids

  1. Amino Silicone Fluids – Excellent softening and anti-static properties; commonly used in textile softeners and hair care products.

  2. Hydroxyl-Terminated PDMS – Reacts with crosslinkers; used in RTV/HTV silicones, coatings, and adhesives.

  3. Vinyl Silicone Fluids – Reactive in addition-curing systems; ideal for elastomers and release coatings.

  4. Epoxy-Modified Silicone Fluids – High adhesion and chemical resistance; used in industrial coatings and sealants.

  5. Polyether-Modified Silicone Fluids – Hydrophilic, emulsifiable; used in personal care, waterborne coatings, and defoamers.

  6. Phenyl-Modified Silicone Fluids – High refractive index, thermal stability; suitable for cosmetics, optics, and high-temperature applications.

Silico® products are available across these categories with controlled molecular weight and purity for consistent performance.

3. Key Performance Parameters for Selection

When selecting functional silicone fluids, consider the following parameters:

  • Viscosity (cSt) – Determines flow, film thickness, lubrication, and damping characteristics.

  • Functional Group Type – Select based on required interaction with substrate or formulation (amino, epoxy, hydroxyl, polyether, phenyl).

  • Compatibility – With aqueous, oil-based, or polymer systems.

  • Thermal & Oxidative Stability – Ensure functional groups remain stable under intended operating temperatures.

  • Application-Specific Properties – Anti-foam, anti-stick, dielectric properties, skin feel, slip, or release performance.

  • Purity and Quality – Low volatility, controlled color, minimal impurities, and stable shelf life.

Application of modified silicone oil

4. Common Applications and Silico® Product Recommendations

Here’s a practical guide to choosing Silico® functional silicone fluids based on industry and application:

Textile Finishing & Softeners

  • Requirements: Softness, anti-static, smooth feel, hydrophilic/hydrophobic adjustment

  • Recommended Silico® Products:

    • Silico® AM-350 – Amino-modified, excellent softness and anti-static performance

    • Silico® PE-500 – Polyether-modified, water-soluble, enhances fabric hydrophilicity and softness

Coatings & Release Agents

  • Requirements: Mold release, anti-stick, high-temperature resistance, smooth gloss

  • Recommended Silico® Products:

    • Silico® EP-800 – Epoxy-modified, high adhesion and temperature resistance

    • Silico® PH-500 – Phenyl-modified, improves heat resistance and surface gloss

Cosmetics & Personal Care

  • Requirements: Skin feel, smoothness, emulsification, low irritation

  • Recommended Silico® Products:

    • Silico® PE-1000 – High molecular weight polyether-modified, excellent emulsification and skin compatibility

    • Silico® OH-200 – Hydroxyl-terminated, low viscosity, improves smoothness and spreadability

Electronics & Electrical Insulation

  • Requirements: High-temperature resistance, dielectric stability, low volatility, long-term reliability

  • Recommended Silico® Products:

    • Silico® PH-700 – Phenyl-modified, excellent dielectric properties and heat stability

    • Silico® DM-500 – High-purity dimethyl silicone, low volatility, suitable for insulation and cooling

Electronics & Electrical Insulation

  • Requirements: Thermal stability, wide temperature range, low volatility, lubrication/damping

  • Recommended Silico® Products:

    • Silico® DM-350 – Standard dimethyl silicone, industrial lubricant and damping applications

    • Silico® PH-450 – Methyl-phenyl silicone, low-temperature lubrication, precision machinery and damping

5. Selection Process: From Requirements to Product Match

  1. Define final application – substrate/system, environment, chemical exposure, mechanical stress

  2. Identify key performance requirements – viscosity, functional group, compatibility, temperature stability

  3. Select modification type – amino, hydroxyl, epoxy, polyether, phenyl

  4. Match Silico® product according to specifications

  5. Conduct trial tests – compatibility, performance, safety, cost-effectiveness

  6. Confirm procurement specifications – storage, delivery, technical support

6. Common Mistakes and Considerations

  • Choosing by viscosity only while ignoring functional group type

  • Ignoring environmental factors – temperature, chemical exposure, substrate

  • Overlooking compatibility with polymers, coatings, or emulsions

  • Neglecting supplier technical support, datasheets, and testing guidance

7. Conclusion: Optimize Performance with the Right Silicone Fluid

Functional silicone fluids are key materials for enhancing product performance across industries.
By understanding types, properties, application needs, and proper selection procedures, engineers and formulators can make precise, high-performance decisions.

Silico® functional silicone fluids offer a comprehensive range of modified silicone oils with reliable quality, tailored to applications from textiles and coatings to cosmetics, electronics, and industrial lubrication.

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